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方向一:能源材料

本团队利用喷雾凝固-喷雾干燥法成功制备了形貌规则的纤维素多孔微球体,实现了在不同pH 值下该微球对消炎药布洛芬的可控释放。利用高温自生压力技术,以液态钛酸酯为前驱物,直接煅烧一步成功制备了碳掺杂的钛酸锂,并成功应用于锂离子电池负极材料。利用喷雾干燥结合超声分解技术,以壳聚糖为前驱物成功制备了多孔碳载体,并将单质银负载到多孔碳载体表面,该材料具有较好的抗菌性能以及催化性能)。以壳聚糖为前驱物结合煅烧技术制备的多孔炭作为载体成功应用在锂-硫电池复合正极的制备。以天然高分子纤维素为前驱物,通过铜氨溶液将其溶解后进行喷雾造粒,成功制备了铜氨纤维复合组分微球,经进一步煅烧成功制备了Cu/炭复合多孔微球材料,该复合微球对有机反应表现出较好的催化活性。利用超高温水热技术,无需高温煅烧后处理技术,一步反应即成功制备了Fe3O4均匀地分散在石墨烯表面的复合结构,该复合组分应用于锂离子电池负极材料,比容量可以达到800 mAh/g 以上。基于上述研究成果,在美国化学会的 Langmuir,ACS sustainable chemistry and Engineering,J. Phys. Chem. A,RSCNew J Chem.,RSC Advances以及Elsevier出版社的Journal of Power Sources,Carbohydrate Polymers等国际学术期刊发表论文60余篇,其中SCIEI收录52篇,影响因子大于3的论文10篇,申报专利5项,授权4项,培养博士和硕士研究生43名,博士后1名。基于该方向的主要研究内容,本团队成员赵修松教授申报并获得山东省泰山学者优势特色学科人才团队领军人才称号,得到省财政3000万经费支持。

 

主要研究项目:

1)      过度金属掺杂磷酸锰锂正极材料的结构与性能研究(国家自然科学基金面上项目)

2)      模板辅助组装法构筑三维多孔石墨烯及其复合物功能材料(国家自然科学基金青年基金)

3)      三维结构BN材料的设计构筑及其在乙炔氢氯化反应中的催化机制研究(国家自然科学基金青年基金)

4)      BaZrO3基质子导体固体氧化物燃料电池阴极的设计与研究(国家自然科学基金青年基金)

5)      海胆状氧化锌中空球/氰酸酯复合材料的制备及介电性能研究(山东省自然科学基金(青年项目))

6)      用于甲烷燃烧的贵金属催化剂的高效利用与替代研究(山东省自然科学基金(博士项目))

7)      石墨烯负载形核剂协同改善硼氢化锂-氢化镁可逆储氢材料的性能及其机理研究(山东省自然科学基金(博士项目))

8)      镍钴锰硫化物多金属组元协同储能机理研究(浙江省自然科学基金)

9)      基于模板方法的石墨烯三维多孔网络结构的构建(青岛市源头创新计划应用基础研究项目)

10)  镍钴锰三金属硫化物的制备及储能机制研究(青岛市创新源头计划项目)

 

获奖及荣誉:

1)     2015年山东高等学校优秀科研成果普通本科自然科学类二等奖:炭基功能复合材料的制备及其储能和催化性能研究

 

近期有代表性的论文:

1.     Peizhi Guo*, Rongyue Wang, Jing Xue, Binghui Xu, Yutao Sang, Hongliang Li, Xiusong Zhao, Assembly of colloidal cuprous oxide nanocrystals and study of its magnetic and electrocatalytic properties, Colloids Surf. A, 2017, 522, 295-303.

2.     Peizhi Guo*, Zhen Li, Shuibo Liu, Jing Xue, Gunglei Wu, Hongliang Li, Xiusong Zhao, Electrochemical properties of colloidal nanocrystal assemblies of manganese ferrite as the electrode materials for supercapacitors, J. Mater. Sci., 2017, 52, 5359-5365.

3.     Jine Liu, Aiping Fu, Yiqian Wang, Peizhi Guo, Hongbin Feng, Hongliang Li*, Xiusong Zhao, Spraying Coagulation-Assisted Hydrothermal Synthesis of MoS2/Carbon/Graphene Composite Microspheres for Lithium-Ion Battery Applications, Chem Electro Chem., 2017, 4, 2027-2036.

4.     Lianying Zhang*, Ze Liu, Graphene decorated with Pd4Ir nanocrystals: Ultrasound-assisted synthesis, and application as a catalyst for oxidation of formic acid, J. Colloid Interface Sci., 2017, 505, 783-788.

5.     Jing Xue, Guangting Han, Wanneng Ye, Yutao Sang, Hongliang Li, Peizhi Guo* and Xiusong Zhao, Structural Regulation of PdCu2 Nanoparticles and Their Electrocatalytic Performance for Ethanol Oxidation, ACS Appl. Mater. Interfaces, 2016, 8, 34497-34505.

6.     Ruixue Ding, Xinyan Wu, Guangting Han, Qinchao Wang, Hailong Lu, Hongliang Li, Aiping Fu, and Peizhi Guo*, Facile Synthesis of Palladium Colloidal Nanocrystal Clusters and Their Enhanced Electrocatalytic Properties, ChemElectroChem, 2015, 2, 427-433.

7.     Xinxin Cheng, Aiping Fu, Hongliang Li*, Yiqian Wang, Peizhi Guo, Jingquan Liu, Jintao Zhang, and Xiusong Zhao, Sustainable Preparation of Copper Particles Decorated Carbon Microspheres and Studies on Their Bactericidal Activity and Catalytic Properties, ACS Sustainable Chem. Eng., 2015, 3, 2414-2422.

 

近期有代表性的发明专利:

1)   一种多孔碳电极材料的制备方法(200910019348.4

2)   一种具有缓释功能的介孔氧化硅微粒复合载体及其制备方法和应用(ZL 201110052824.X)

3)   一种制备碳包覆磷酸铁锂锂离子电池正极复合材料的高压、低温方法(201310091097.7)

4)   一种制备原位掺碳锂离子电池负极材料钛酸锂的方(ZL201310090925.5

5)   一种制备纤维素微球及壳聚糖包覆的纤维素复合微球的方法(ZL201310483411.6)

6)   一种高温溶剂热一步制备Fe3O4/石墨烯锂离子电池复合负极材料的方法(ZL201410441514.0)

7)   一种用于无机球形纳米颗粒聚集体的显色方法(ZL201510148672.1)

8)   一种类石墨烯二维纳米片的制备方法(ZL201410612347.1)

9)   一种具有超疏水性质的响应性油水分离网膜及其制备方法(CN104117287A)

 

 

方向二:杂化材料

近十年的代表性论文:

1. Jiao, J.; Yang, H.; Fang, C.; Tang, J.; Wang, Y.; Huang, L.; Liu, J.; Wang, W.; Gai, S.; Li, Y.; Kipper, M. J.; Belfiore, L. A., Facile Synthesis, Formation Mechanism and Tunable Upconversion Luminescence of Nanocrystals Co-Doped by Yb3+/Tm3+.Materials Research Bulletin 2017, 87, 48-53.

2. Shen, W.; Tang, J.; Wang, Y.; Liu, J.; Huang, L.; Chen, W.; Yang, L.; Wang, W.; Wang, Y.; Yang, R.; Yun, J.; Belfiore, L. A., Strong Enhancement of Photoelectric Conversion Efficiency of Co-Hybridized Polymer Solar Cell by Silver Nanoplates and Core-Shell Nanoparticles. ACS applied materials & interfaces 2017, 9(6), 5358-5365.

3. Wang Y.X, Huang L, Tang J, et al. Melt Spinning Fibers of Isotactic Polyproplene Doped with Long-Lifetime Luminescent Inorganic-Organic SiO2-Eu3+Hybrid Nanoparticles. Materials Letters. 204 (2017) 31-34.

4. Wang, Y.; Huang, L.; Tang, J.; Wang, Y.; Li, X.; Ma, W., Luminescent Polyacrylonitrile(Pan) Electrospinning Nanofibers Encapsulating Silica Nanoparticles Carried Ternary Europium Complex. International Journal of Electrochemical Science 2016, 11(3), 2058-2065.

5. Wang, X.; Tang, J.; Wang, Y.; Wang, Y.; Huang, Z.; Liu, J.; Huang, L.; Jiao, J.; Wang, D.; Shen, W.; Song, Y.; Belfiore Laurence, A., Eu()Induced Diblock Polymer Self-Assembling and Its Luminescent Property. New Chemical Materials 2016, 44(6), 69-71,74.

6. Song, Y.; Tang, J.; Wang, Y.; Wang, X.; Wang, D.; Huang, L.; Liu, J.; Jiao, J.; Belfiore Laurence, A., Europium()-Induced Self-Assembly Behaviors of Ps-B-P4vp Diblock Copolymers and Their Characterization.Engineering Plastics Application 2016, 44(2), 1-6.

7. Shen, W.; Tang, J.; Wang, D.; Yang, R.; Chen, W.; Bao, X.; Wang, Y.; Jiao, J.; Wang, Y.; Huang, Z.; Huang, L.; Liu, J.; Wang, W.; Wu, P.; Belfiore, L. A., Enhanced Efficiency of Polymer Solar Cells by Structure-Differentiated Silver Nano-Dopants in Solution-Processed Tungsten Oxide Layer.Materials Science and Engineering B-Advanced Functional Solid-State Materials 2016, 206, 61-68.

8. Li, Y.; Tang, J.; Huang, L.; Liu, J.; Wang, Y.; Ge, X.; Wang, L.; Li, G.; Sun, W., Effective Exfoliation of Expanded Graphite in Rigid Poly(Methyl Methacrylate) and Its Dispersion and Enhancement in Poly(Vinylidene Fluoride). Journal of Nanoscience and Nanotechnology 2016, 16(9), 10021-10028.

9. Jiao, J.; Qiu, W.; Tang, J.; Chen, L.; Jing, L., Synthesis of Well-Defined Fe3o4 Nanorods/N-Doped Graphene for Lithium-Ion Batteries. Nano Research 2016, 9(5), 1256-1266.

10. Hou, Y.; Huang, L.; Wang, Y.; Tang, J.; Liu, J.; Wang, Y.; Jiao, J.; Wang, W.; Zhao, Y., Preparation of Graphene /Silver Hybrid Materials and Research of Raman Enhanced Performance. Applied Chemical Industry 2016, 45(5), 806-809.

11. Wang, Y.; Tang, J.; Zheng, H.; Sun, W.; Jiao, J.; Wang, Y.; Huang, L.; Liu, J.; Wang, W.; Shen, W.; Zhuang, H.; Belfiore, L. A., Crystallization of Poly(Ethylene Terephthalate) Via Silica Nanoparticles Tethered with Short Diblock Peg-Pet Copolymers. Science of Advanced Materials 2016, 8(8), 1603-1611.

12. Wang, Y.; Tang, J.; Xie, S.; Liu, J.; Xin, Z.; Liu, X.; Belfiore, L. A., Leveling Graphene Sheets through Electrospinning and Their Conductivity. RSC Advances 2015, 5(52), 42174-42177.

13. Wang, X.; Tang, J.; Xu, Q.; Shen, W.; Wang, Y.; Liu, J.; Wang, Y.; Huang, L.; Jiao, J.; Wang, D.; Song, Y.; Belfiore, L. A., Fluorescent Polymeric Aggregates Induced by Eu3+ Ions and Their Surface Morphologies. Optical Materials 2015, 46, 28-33.

14. Wang, J.; Huang, Z.; Tang, J.; Wang, Y.; Liu, J.; Huang, L.; Liu, H.; Belfiore Laurence, A., Study on Preparation of Ternary Complex of Europium Coated Ag@SiO2Nanoconposite and Its Modification Research of PP. Engineering Plastics Application 2015, 43(6), 22-25.

15. Wang, D.; Tang, J.; Wang, X.; Shen, W.; Wang, Y.; Wang, Y.; Liu, J.; Huang, L.; Jiao, J.; Song, Y.; Belfiore, L. A., Morphology and Luminescent Properties of Solid Micelles Based on Europium(Iii) Complexes with Diblock Copolymers of Methyl Methylacrylate and Acrylic Acid. Ferroelectrics 2015, 486(1), 91-105.

16. Shen, W.; Xiao, M.; Tang, J.; Wang, X.; Chen, W.; Yang, R.; Bao, X.; Wang, Y.; Jiao, J.; Huang, L.; Liu, J.; Wang, W.; Belfiore, L. A., Effective Regulation of the Micro-Structure of Thick P3ht:Pc71bm Film by the Incorporation of Ethyl Benzenecarboxylate in Toluene Solution. RSC Advances 2015, 5(59), 47451-47457.

17. Li, Y.; Tang, J.; Huang, L.; Wang, Y.; Liu, J.; Ge, X.; Tjong, S. C.; Li, R. K. Y.; Belfiore, L. A., Facile Preparation, Characterization and Performance of  Noncovalently Functionalized Graphene/Epoxy Nanocomposites with Poly(Sodium 4-Styrenesulfonate). Composites Part a-Applied Science and Manufacturing 2015, 68, 1-9.

18. Jiao, J.; Tang, J.; Wang, G.; Wang, Y.; Huang, L.; Huang, Z.; Liu, J.; Zhu, Y.; Belfiore, L. A., Synthesis of Photocatalytic Hematite Nanotube Array Using a Template-Free Solvothermal Approach. RSC Advances 2015, 5(75), 60920-60925.

19. Jiao, J.; Tang, J.; Gao, W.; Kuang, D.; Tong, Y.; Chen, L., Plasmonic Silver Nanoparticles Matched with Vertically Aligned Nitrogen-Doped Titanium Dioxide Nanotube Arrays for Enhanced Photoelectrochemical Activity. Journal of Power Sources 2015, 274, 464-470.

20. Wang, R.; Tang, J.; Kong, N.; Wang, Y.; Liu, J.; Liu, J., A Nano-Silver Enhancement Effect on the Luminescence of a Ligand-Eu3+ Complex Via a SiO2 Spacer. Australian Journal of Chemistry 2014, 67(4), 644-650.

21. Tang, J.; Niu, L.; Liu, J.; Wang, Y.; Huang, Z.; Xie, S.; Huang, L.; Xu, Q.; Wang, Y.; Belfiore, L. A., Effect of Photocurrent Enhancement in Porphyrin-Graphene Covalent Hybrids. Materials Science & Engineering C-Materials for Biological Applications 2014, 34, 186-192.

22. Shen, W.; Tang, J.; Yang, R.; Cong, H.; Bao, X.; Wang, Y.; Wang, X.; Huang, Z.; Liu, J.; Huang, L.; Jiao, J.; Xu, Q.; Chen, W.; Belfiore, L. A., Enhanced Efficiency of Polymer Solar Cells by Incorporated Ag-SiO2 Core-Shell Nanoparticles in the Active Layer. RSC Advances 2014, 4(9), 4379-4386.

23. Liu, H.; Tang, J.; Wang, Y.; Huang, L.; Wang, Y.; Jiao, J.; Liu, J.; Xin, Z.; Belfiore, L. A., Effect of Water-Absorbing Nanospheres on Antistatic Property of Isotactic Polypropylene Fibers. Journal of Applied Polymer Science 2014,131(15).

24. Jiao, J.; Xia, J.; Qiu, W.; Tang, J.; Li, G.; Kuang, D.; Tong, Y.; Chen, L., Hierarchical Tree-Like Heterostructure Arrays for Enhanced Photoeletrochemical Activity. Electrochimica Acta 2014, 136, 217-222.

25. Huang, L.-J.; Wang, Y.-X.; Wu, D.-C.; Tang, J.-G.; Wang, Y.; Liu, J.-X.; Huang, Z.; Jiao, J.-Q.; Liu, J.-Q., Electrode Properties and the Dehydrogenation Process of Amorphous Mg-Ni-La Alloys. Journal of Power Sources 2014,249, 35-41.

26. Huang, L.; Wang, Y.; Tang, J.; Wu, D.; Wang, Y.; Liu, J.; Huang, Z.; Jiao, J.; Liu, J., Hydrogen-Storage Mechanism of Amorphous Mg-Ni-La Hydrogen-Storage Alloys in Electrochemical Absorbtion/Desorbtion Process. The Chinese Journal of Nonferrous Metals 2014, 24(12), 3059-3065.

27. Xu, Q.; Tang, J.; Wang, Y.; Liu, J.; Wang, X.; Huang, Z.; Huang, L.; Wang, Y.; Shen, W.; Belfiore, L. A., Eu3+-Induced Aggregates of Diblock Copolymers and Their Photoluminescent Property. Journal of Colloid and Interface Science 2013, 394, 630-638.

28. Xu, Q.; Tang, J.; Wang, Y.; Liu, J.; Huang, Z.; Huang, L.; Li, A.; Wang, Y.; Belfiore, L. A., Embedding Copper Nanoparticle-Anchored Conductive Nano-Blocks in Polyelectrolyte. Particuology 2013, 11(6), 748-752.

29. Xiong, L.; Liu, J.; Tang, J.; Wang, Y.; Wang, Y.; Zhu, Q.; Huang, L.; Huang, Z., The Preparation of a Metal and Polymer Composite Conductive Materials. New Chemical Materials 2013, 41(2), 24-26.

30. Xie, S.; Tang, J.; Huang, L.; Liu, J.; Wang, Y.; Wang, H., Synthesis of Graphene Oxide by High Temperature Annealing Method. New Chemical Materials 2013,41(4), 53-55.

31. Wang, Y.; Tang, J.; Liu, H.; Wang, Y.; Liu, J.; Huang, L.; Huang, Z.; Xu, Q.; Xiong, L.; Liang, Y., Using Vesicle-Like Structures of Amphiphilic Block Copolymer as an in-Situ Reactor for Preparing Nanosized Silver Composite Materials. Journal of Functional Materials 2013, 44(11), 1584-1587.

32. Wang, Y.; Tang, J.; Huang, L.; Wang, Y.; Huang, Z.; Liu, J.; Xu, Q.; Shen, W.; Belfiroe, L. A., Enhanced Emission of Nanosio(2)-Carried Eu3+Complexes and Highly Luminescent Hybrid Nanofibers. Optical Materials 2013,35(7), 1395-1403.

33. Huang, L.; Wang, Y.; Tang, J.; Wu, D.; Wang, Y.; Liu, J., Capacity Fading Mechanism for Mg-Based Amorphous Electrode Alloys. Chinese Journal of Rare Metals 2013, 37(1), 14-20.

34. Yang, B.; Tang, J.; Yang, P.; Wang, Y.; Liu, J.; Liu, H.; Wang, R.; Huang, Z.; Liu, J.; Belfiore, L. A., Microporous Network-Assisted Formation of Copper-in-Polymer Gradient Composite Film. Journal of Applied Polymer Science 2012, 126(2), 706-712.

35. Tang, J.; Yang, B.; Liu, J.; Wang, Y.; Huang, L.; Huang, Z.; Wang, Y.; Zhu, Q.; Belfiore, L. A., Electric-Field-Actuation of in Situ Composites That Contain Silver-Coated Carbon Fibers in Sodium Sulfonate Ionomers. RSC Advances 2012,2(23), 8813-8820.

36. Luo, J.; Tang, J.; Xiong, L.; Liu, J.; Wang, Y.; Huang, L.; Huang, Z., Effects of Ph Value on Synthesis of Polyphenylpropiolic Acid. Journal of Functional Materials 2012, 43(10), 1255-1257,1262.

37. Li, A.; Liu, J.; Tang, J.; Liu, J.; Wang, Y.; Xu, Q.; Wang, Y., Synthesis of Amphiphilic Block Copolymer by Raft Polymerization and It′s Induced Self-Assembly. The Journal of Engineering Plastics Application 2012,40(5), 17-21.

38. Wang, R.; Tang, J.; Liu, J.; Wang, Y.; Huang, Z., Preparation of Ag@SiO2Dispersion in Different Solvents and Investigation of Its Optical Properties. Journal of Dispersion Science and Technology 2011, 32(4), 532-537.

39. Wang, F.; Tang, J.; Liu, J.; Wang, Y.; Wang, R.; Niu, L.; Huang, L.; Huang, Z., Highly Efficient Photoinduced Electron Transfer in a Novel Tetrakis(Tetraphenylporphyrinatozinc)/Perylenetetracarboxidiimide Array and Its Application to a Photovoltaic Device. Bulletin of the Chemical Society of Japan 2011, 84(4), 427-436.

40. Wang, F.; Tang, J.; Liu, J.; Wang, Y.; Wang, R.; Niu, L.; Huang, L.; Huang, Z., Synthesis and Photoinduced Electron Transfer Characteristic of a Bis (Zinc Porphyrin)-Perylene Bisimide Array. Journal of Physical Organic Chemistry 2011,24(11), 1101-1109.

41. Menglong, D.; Jianguo, T.; Jixian, L. I. U.; Yao, W.; Linjun, H.; Yumin, F.; Shiqiang, X. I. E.; Zhen, H., Study on Mechanical Properties of Trans-1,4-Polyisoprene/Graphene Nanocomposite. Modern Chemical Industry 2011,31(5), 42-44.

42. Yang, B.; Tang, J.; Liu, J.; Wang, Y.; Dong, M.; Niu, L., Preparation of Graphene Nanosheets/Styrene-Acrylic Emulsion Hybrid Conductive Film. Paint & Coatings Industry 2010, 40(9), 5-8.

43. Tang, J.; Yang, H.; Liu, J.; Wang, Y.; Yin, X.; Wang, R.; Huang, L.; Huang, Z., Ln(3+)-Enhanced Blue Fluorescence from Novel Excimer of 1,8-Naphthalimide-Conjugated Pamam. Optical Materials 2010, 32(11), 1417-1422.

44. Liu, J.; Tang, J.; Xu, S.; Wang, Y.; Liu, J.; Gong, K., Synthesis and Properties of Phenylpropiolic Acid Oligomers. Acta Polymerica Sinica 2010, (1), 45-50.

45. Huang, Z.; Tang, J.; Wang, Y.; Liu, J.; Huang, L.; Wang, R.; Huang, L., Rheological Behavior of Pp Filled with Nano-Silica Surface Coating Modified by Organic Lanthanide Complex. Plastics 2010, 39(5), 24-27.

46. Huang, L.; Feng, Y.; Tang, J.; Liu, J.; Wang, Y.; Hao, J., High Transparent Agricultural Film Containing Silica for Anti-Fogging. New Chemical Materials2010, 38(3), 103-105.

47. Wang, L.; Wang, Y.; Tang, J.; Liu, J.; Huang, Z.; Wang, R., Study on Preparation and Properties of Poly(Ethylene Glycol)-Modified Nano-SiO2. In Journal of Scientific Conference Proceedings, Vol 1, Nos. 2 and 3, Wang, H.; Hie, J. R. H.; Zhang, J., Eds. 2009, pp 268-271.

48. Kong, L.; Tang, J.; Liu, J.; Wang, Y.; Wang, L.; Cong, F., Fluorescent Nanoblocks of Lanthanide Complexes on Nano Silicon Dioxide and Carbon Nanotube Donors with Ligand-Antenna Integration (Ali) Structure. Materials Science & Engineering C-Biomimetic and Supramolecular Systems 2009, 29(1), 85-91.

49. Zhao, F.; Tang, J.; Wang, Y.; Liu, J.; Song, Z.; Wang, R.; Huang, Z., Praperation and Characterization of Ph Sensitive Pmaa-Grafted PVDF Microporous Membrane. New Chemical Materials 2008, 36(6), 50-51,84.

50. Yao, W.; Lingyuan, W.; Jianguo, T.; Bo, Y., Preparation and Properties of Pet-PEG-SiO2Co-Polymerized Hybrid Nanoblocks. Journal of Materials Engineering 2008, (10), 101-105.

51. Hui, Y.; Jianguo, T.; Yao, W.; Jixian, L. I. U.; Linguang, Z.; Jia, L. I. U., Synthesis and Fluorescent Property of Polyamidoamine Dendrimer Modified by Naphthalimide. Applied Chemical Industry 2008, 37(5), 465-468.

52. Tang, J.; Huang, X.; Wang, Y.; Liu, J., Effect of Ligand-Antenna Integration (Ali) in Macromolecular Structures on Fluorescent Property of Processable Macromolecule-Lanthanide Complexes. Optical Materials 2007, 29(12), 1774-1781.

 

专利:

1.唐建国,黄兴溢,王瑶.可溶性大分子与稀土复合激光材料的制备方法.

2.唐建国,杨培花,王瑶.一种制备聚合物基金属梯度复合材料的方法.

3.唐建国;丛菲;刘继宪;王瑶;黄林军;张磊.一种功能纳米石墨烯的制备方法.

4.唐建国;杨波;刘继宪;王瑶;黄林军;庄娜;廖金龙.一种离子聚合物-金属机敏店驱动复合材料的制备方法.

5.唐建国;刘红星;王瑶;黄林军;刘继宪;焦吉庆;黄震;王彦欣;孙文建.一种利用超吸水微纳米球制备抗静电纤维的方法.

6.王瑶;刘继宪;唐建国;纪小红.一种叶酸巯基化衍生物的制备方法

7.王瑶,唐建国,许青松,刘继宪,黄林军,黄震,王彦欣.一种聚合物-稀土离子发光胶束的制备方法.

8.唐建国、熊磊、刘继宪、王瑶.一种嵌段高分子-纳米金属薄层复合导电材料的制备方法.

9.刘继宪;孙燕;唐建国;王瑶;黄震;黄林军;武鹏.一种巯基化叶酸及其制备方法.

10.黄林军,王彦欣,唐建国,王瑶,刘继宪,黄震.Mg-Ni-Nd系贮氢电极合金的表面改性方法.

11.王瑶,唐建国等.一种溶液法合成嵌段聚合物纳米二氧化硅的方法.

12.焦吉庆,唐建国等.一种非模板制备α-Fe2O3中空管状纳米薄膜的方法.

13.唐建国,王蝶等.一种有机稀土固体胶束及其制备方法和提高太阳能电池转化效率的方法.

 

省部级科研奖励:

1.      山东省齐鲁友谊奖Laurence A. Belfiore, 2016

2.      青岛市国际合作奖Mathew Jay Kipper2016

3.      青岛市突出贡献奖Wickramsinghe2015

4.青岛市国际合作奖Jong-Leng Liow2010

5.山东省高等学校自然科学二等奖,高分子基金属复合材料的制备、结构与性能研究;

6.山东省高等学校自然科学一等奖,复合材料中相斥组元纳米尺度的形态结构设计与实证;

7.青岛市自然科学奖三等奖,相斥组元纳米尺度复合材料的结构设计与实证研究;

8.山东省高等学校自然科学二等奖,高分子-金属复合材料的相界结构生成原理与功能材料。

 

 

方向三:石墨烯材料

代表性论文:

1)       Hierarchical coral-like NiMoS nanohybrids as highly efficient bifunctional  electrocatalyst for overall urea electrolysis, Nano Research, 2017, DOI 10.1007/s12274-017-1711-3.

2)       Fabrication of an arbitrary-shaped and nitrogen-doped graphene aerogel for highly compressible all solid-state supercapacitors, Journal of Materials Chemistry A, 2017, DOI 10.1039/C7TA04917J.

3)       Simultaneous enhancement of bioactivity and stability of laccase by Cu2+/PAA/PPEGA matrix for efficient biosensing and recyclable decontamination of pyrocatechol, Analytical Chemistry, 2017, 89(3), 2065-2072.

4)       Boron Nitride Quantum Dots with Solvent-Regulated Blue/Green Photoluminescence and Electrochemiluminescent Behavior for Versatile Applications, Advanced Optical Materials, 2017,1600661.

5)       In situ electrochemical surface derivation of cobalt phosphate from Co(CO3)0.5(OH)0.11H2O nanoarray for efficient water oxidation in neutral aqueous solution,Nanoscale, 2017, 9, 3752-3756

6)       Soluble, Exfoliated Two-dimensional Nanosheets as Excellent Aqueous Lubricants,ACS Applied Materials & Interfaces, 2016, 8 (47), 32440-32449.

7)       Fabrication of Hollow Metal ‘Nano-caps’ and Their Red-Shifted Optical Absorption Spectra, Advanced Materials, 2005, 17, 1276-1281.

8)       Cortie Anisotropic Optical Properties of Semi-Transparent Coatings of Gold Nano-Caps, Advanced Functional Materials, 2006, 16 (11): 1457-1461.

9)       In-Situ Formation of Protein-Polymer Conjugates via Reversible Addition Fragmentation Chain Transfer Polymerization,Angewandte Chemie International Edition, 2007, 46, 3099-3103.

10)   Bio-application of RAFT Polymerization. Chemical Review, 2009, 109, 5402-5436.

 

 

方向四:生物医用材料

代表性论文:

1.   Rational Design of Cancer Nanomedicine: Nanoproperty Integration and Synchronization. ADVANCED MATERIALS,DOI: 10.1002/adma.201606628.

2.   Esterase-Activated Charge-Reversal Polymer for Fibroblast-Exempt Cancer Gene Therapy. ADVANCED MATERIALS, DOI: 10.1002/adma.201603095.

3.   Fusogenic Reactive Oxygen Species Triggered Charge-Reversal Vector for Effective Gene Delivery. ADVANCED MATERIALS, DOI: 10.1002/adma.201504288.

4.   Integration of Nanoassembly Functions for an Effective Delivery Cascade for Cancer Drugs. ADVANCED MATERIALS, DOI: 10.1002/adma.201401554.

5.   Tumor Redox Heterogeneity-Responsive Prodrug Nanocapsules for Cancer Chemotherapy. ADVANCED MATERIALS, DOI: 10.1002/adma.201300929.

6.   Intracellularly Disintegratable Polysulfoniums for Efficient Gene Delivery. ADVANCED FUNCTIONAL MATERIALS, DOI: 10.1002/adfm.201606826.

7.   Macromolecular MRI contrast agents: Structures, properties and applications. PROGRESS IN POLYMER SCIENCE,DOI: 10.1016/j.progpolymsci.2012.07.001.

8.   Molecularly Precise Dendrimer-Drug Conjugates with Tunable Drug Release for Cancer Therapy. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, DOI: 10.1002/anie.201406442.

9.   Acid-Active Cell-Penetrating Peptides for in Vivo Tumor-Targeted Drug Delivery. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, DOI: 10.1021/ja311180x.

10. Prodrugs Forming High Drug Loading Multifunctional Nanocapsules for Intracellular Cancer Drug Delivery. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, DOI: 10.1021/ja909475m.

 

 

方向五:纤维新材料

2004年以来,海藻纤维新材料研究团队研究先后获得了国家863重点项目(2003AA333050)、973专项、国家自然科学基金、山东省自主创新专项、山东省重大成果转化专项、青岛市关键技术攻关等国家、省、市级近50项的资助,专利40余项,发表学术论文200余篇。2010年团队入选了教育部长江学者和创新团队发展计划创新团队。入选山东省优秀创新团队,并被山东省人民政府记集体一等功。2013年,作为主要参与团队申报成功并着手建设“2011计划山东省海洋生物质纤维材料及纺织品协同创新中心2013年作为必威betway手机官网主要参与团队成功申报“2013年泰山学者优势特色学科人才团队支持计划2015年入选了教育部长江学者和创新团队发展计划滚动支持计划。

 

主要研究项目:

(1)      海藻酸盐水溶液的液晶行为研究及其液晶纺丝探索(国家自然科学基金)

(2)      海藻酸钠对碳纳米管的分散及其液晶纺丝成型(国家自然科学基金)

(3)      海藻酸钠溶液的液晶行为与高效纺丝(山东省重点研发计划项目)

(4)     碳基纳米粒子/海藻酸钠的协同效应及其新型功能纤维的构建(青岛市应用基础研究计划重点项目)

(5)     海藻资源制取纤维及深加工关键技术开发(863计划重点项目)

(6)     千吨级短流程纺织专用海藻纤维生产线产业化示范(山东省科技厅山东省自主创新专项)

(7)     高浓度海藻酸盐溶液的制备、流变性能及液晶性研究(973计划前期)

 

获奖及荣誉:

(1)     2013年获山东省高校优秀科研成果奖三等奖(第一位):基于嵌段共聚物的多功能纳米复合材料制备及性能

(2)     2012山东省齐鲁巾帼发明家优秀奖(第一位)

(3)     2012年获山东省高校优秀科研成果奖二等奖(第一位):碳纳米管的功能改性及其应用

(4)     2011年山东省高校优秀科研成果奖三等奖(第一位):碳纳米管的分散及其功能复合材料的制备

(5)     2016年度中国纺织工业联合会科学技术奖一等奖:海藻纤维制备产业化成套技术及装备

(6)     教育部海洋生物质纤维新材料长江学者和创新团队核心成员

(7)     山东省“海洋纤维新材料”优秀创新团队,集体一等功

 

近期有代表性的论文:

(1)   Zhao, Congxian ;  Zhang, Chao ;  Kang, Hongliang;  Xia, Yanzhi;  Sui, Kunyan*; Liu, Ruigang. Gelation of Na-alginate aqueous solution: A study of sodium ion dynamics via NMR relaxometry. Carbohydrate Polymers, 2017, 169, 206-212.

(2)   Chen, JianwenCui, XihuaSui, Kunyan*Zhu, YutianJiang, WeiBalance the electrical properties and mechanical properties of carbon black filled immiscible polymer blends with a double percolation structure. Composites Science and Technology, 2017, 140, 99-105.

(3)   Tan, Yeqiang; Zhang, Wenqian; Li, Yanhui;   Xia, Yanzhi; Sui, Kunyan*.Grafting of multi-sensitive PDMAEMA brushes onto carbon nanotubes by ATNRC: tunable thickening/thinning and self-assembly behaviors in aqueous solutions. RSC Advances, 2016, 6, 92305-92315.

(4)   Ma, Yingying; Huang, Jian; Sui, Kunyan*; Wang, Guowei. Synthesis and Characterization of Crystalline Graft Polymer Poly(ethylene oxide)-g- poly(epsilon-caprolactone)(2) with Modulated Grafting Sites. J Polm Sci Part A: Polym Chem, 2014, 52, 2239-2247.

(5)   Sui, Kunyan*;Zhao, Xin;Wu, Zhiming;Xia, Yanzhi;Liang, Hongchao;Li, Yujin. Synthesis, Rapid Responsive Thickening, and Self-Assembly of Brush Copolymer Poly(ethylene oxide)-graft-Poly(N,N-dimethylaminoethyl methacrylate) in Aqueous Solutions. Langmuir, 2012, 28, 153-160.

(6)    Sui, Kunyan*;Li, Yujin;Liu, Rongzhan;Zhang, Yang;Zhao, Xin;Liang, Hongchao;Xia, Yanzhi.Biocomposite fiber of calcium alginate/multi-walled carbon nanotubes with enhanced adsorption properties for ionic dyes. Carbohyd Polym, 2012, 90, 399-406.

(7)   Zhao, Xin; Sui, Kunyan*; Wu, Wenwen; Liang, Hongchao;  Li, Yujin;  Wu, Zhiming;  Xia, Yanzhi. Synthesis and properties of amphiphilic block polymer functionalized multi-walled carbon nanotubes and nanocomposites. Compos Part A-Appl S, 2012, 43, 758-764.

(8)   Sui, Kunyan*;Liang, HongchaoZhao, XinMa, YingyingZhang, YangXia, Yanzhi. Synthesis of amphiphilic poly(ethylene oxide-co-glycidol)-graft- polyacrylonitrile brush copolymers and their self-assembly in aqueous media. Macromol Chem Phys, 2012, 213, 1717-1724.

(9)   Sui, Kunyan*;Gao, Song;Wu, Wenwen;Xia, Yanzhi. Injectable supramolecular hybrid hydrogels formed by MWNT-grafted- poly(ethylene glycol) and α-cyclodextrin. J Polm Sci Part A: Polym Chem, 2010, 48, 3145-3151.

(10)            Sui, Kunyan*;Shan, Xin;Gao, Song;Xia, Yanzhi;Zheng, Qiang;Xie, Dan. Dual-responsive supramolecular inclusion complexes of block copolymer poly(ethylene glycol)-block-poly[(2-dimethylamino)ethyl methacrylate] with α-cyclodextrin. J Polm Sci Part A: Polym Chem, 2010, 48, 2143-2153.


近期有代表性的发明专利:

(1)   一种碳基纳米粒子海藻酸钠多功能高性能复合纤维及其制备方法(ZL 201410399097.8

(2)   一种气体敏感性金属纳米粒子可逆分形聚集体的制备方法 (ZL 201410399158.0)

(3)   含有金纳米粒子的分形树枝图案聚集体的制备方法 (ZL 201410320833.6)

(4)   一种海藻酸或海藻酸盐液晶膜的制备方法及应用(ZL201310699754.6

(5)   一种海藻酸钠/碳纳米管复合纤维的制备方法(ZL201010100026.5)

(6)   一种改性碳纳米管的制备方法(ZL200910015124.6)

(7)   一种分散碳纳米管的简易方法(ZL200810159729.8

(8)   含碳纳米管的接枝聚合物的制备方法(ZL200810013869.4